Spectrometer Resolution
Spectral resolution
The spectral resolution or resolving power of a spectrograph is a measure of its ability to resolve features in the electromagnetic spectrum. The resolving power is understood as the inverse relative spectral resolution, e.g. the wavelength divided by the smallest wavelength difference that can be distinguished by the spectrograph. When relating to spectrometry, the term chromatic resolving power is often used.
The image a distant point source forms at the focal plane of an optical telescope lens or camera lens is actually a Fraunhofer diffraction pattern. The lens opening plays the role of the aperture. The image formed by an extended composite source is therefore a superposition of many airy disks. The resolution of a detail in the image therefore depends on the size of the individual Airy disks. If D is the diameter of the lens opening, then the angular radius of an Airy disk is approximately 1.22 l/D. This is also the approximate minimum angular seperation between two equal point sources such that they can be just barely resolved, because at this angular separation the central maximum of the image of one source falls on the first minimum of the other. This condition for optical resolution is known as the Rayleigh criterion.
In the case of a rectangular aperture, of width b, such as the entrance and exit slits or a spectrograph, the minimum angular separation according to the Rayleigh criterion is just l/b. The intensity of the saddle point is 8/p2=0.81 times the maximum intensity.
For instruments based on multiple beam interferences, such as the Fabry-Perot interferometer, the Taylor criterion is more convenient to use, because there are no fringes used for the definition of the local minimum. According to this convention, two equal lines are considered resolved if the individual curves cross at the half intensity, point or either line alone.
The two conventions are often not clearly distinguished, and many people use the Taylor criterion still referring to Lord Raleigh. In real life, the capability of distinguishing between to separate spectral feature depends not only on their separation, but also on the signal to noise ratio. For noisy signals, the "real" resolution may be much worse then the Rayleigh or Taylor criteria would predict. If the signal to noise ratio is high, data processing technique may allow separating two spectral features much closer than their Full Width at Half Maximum (FWHM). The latter statement is particularly true more information on the expected line shapes is available than just the experimental results.
TOP
Resolution
As stated above spectral resolution expresses the ability, for an optical system, to resolve near lines, for example an analytical line and a line of the matrix. To carry out an analysis without the need for numerous inter-element corrections, adequate resolution is necessary, hence a grating with a large number of lines.
Spectral resolution can be improved by reducing the width of the spectral slits, but signal strength (luminosity) is also reduced.
For a given grating and in a given order, the spectral resolving power is proportional to the focal length of the optical system and to the reciprocal of the entrance and exit slit widths. It is exactly the opposite for system brightness.
To achieve the resolution necessary for analyses, one can increase either the focal length of the system for a given grating, or the number of lines of the grating for a given focal length.
However, when the system's focal length is increased, its mechanical stability may be impaired and, for the same grating, brightness is reduced. Stability is a critical characteristic for equipment which must retain its calibration characteristics over a long period of time. Further, brightness is invaluable as it is synonymous with good detection limits
Author: Jean Charles Lefebvre, Horiba Jobin-Yvon
First published on the web: 15 November 1999.
TOP
Signal to Background
Signal to background ratio is reduced at constant resolution when the bandwidth is increased.
Spectral Interference (Peak Overlap)
At high resolution, peaks can be well separated, eg As and Cd lines at 288.8 nm (0.005 nm resolution):
But at low resolution, spectral processing is necessary to reduce spectral interference, eg As and Cd lines at 288.8 nm (low resolution):
First published on the web: 15 May 2000.
Last modified:
13 April, 2007
Author: Geoff Tyler, Horiba Jobin-Yvon , France
TOP